Research Group of Uranium Extraction from Seawater, Institute of Environmental Chemistry, Shanghai
1980, 03(3)
摘要:Extraction of uranium from seawater is one of the important respects in energy development. In this paper, three cardinal aspacts, namely preparation of the adsorbents, adsorption installation, desorption and purification are briefly described.Preparation of the adsorbents is of most essential in uranium extraction from seawater. Three kinds of adsorbent, consisted of hydrated titanium oxide, aluminium hydroxide and ion-exchange resin-508 were developed, and the relations between the adsorption efficiency and the surface structure of adsorbents were investigated. In the meantime the tide-type adsorption installation and the technology of desorption and purification was tried, and the approach of its industrialization was also prospected.
The Research Laboratory of Seawater Resources Chemistry, Shanghai Normal University
1980, 03(3)
摘要:The relationship between the chemico-physical properties of basic zinc carbonate and the efficiency of adsorption of uranium from seawater has been studied. These results have shown that uranium in seawater is mainly present as hydrolyzed complex anion. Both uranium and the adsorbent are solvated in seawater. They gradually share a part of their liquid membrane when coming into contact forming a surface hydroxyl compound, thus lowering the ζ potential of adsorbent.
摘要:The production of carrier-free gallium-67 at external target of the 1.2M cyclotron is described. It was produced by bombardment of natural copper with 26.8 MeV α and natural zinc with 13.4 MeV deuterium, gave thick-target yields of 165μCi/μAh and 350µCi/μAh, respectively. Radiochemical separation of carrier-free gallium-67 from target was carried out by isopropyl ether extraction. Gallium-67 citrate injection was prepared by sodium citrate leaching. The overall chemical procedure took 4 hours and the operations were simple and safe. The chemical yield was greater than 90%.
摘要:A desk instrument of radioisotope X-ray fluorescence analysis is described, which has been used to determine the content of CaO and Fe2O3 in cement specimens, with an precision of 0.14% and 0.02% respectively. The comparison between the results of instrumental and chemical analysis shows that, the specimens of which both results are agreeable within ±0.25% deviation for Cao and within ±0.10% deviation for Fe2O3 amount to about 80% and above 90% of the total respectively. After the determination of CaO content in the "ground cement" and its raw material, the examination of clinker component can be performed, with an error less than 1.5%.
摘要:The technique of radio-fluorography used for silica-gel TLC and polyacrylamide TLC is described. It has the advantages of short time of exposure, high resolution and sensitivity. At the optimal temperature of - 70℃, with added xylene scintillator mixture, the sensitivity may be increased about 100 times as compared with the usual radioautography.
Ma Li-yun,Chen Kun-ming,Zhang Mo-ling,Li yu-qi,Wu jin-hui,Wang Jun-sheng,Di Jia-hai,Yang Ren-kui,Fang Pei-kua
1980, 03(3)
摘要:An oxidant (chloramine-T) on the reaction polypeptide hormones in labelling with Na l25I. The influence of dosage of oxidant (chloramine-T) volume, temperature and pH of the solution in labelling certain polypeptide hormones were investigated. The effect of storage time on immunological activity was also studied.
摘要:This paper gives experimental results of the thermoluminescence of 60Co γ-ray irradiated quartz silica. Its glow curve contains five peaks. The glow peaks have peak temperatures of about 50-60℃, 75-100℃, 110-160℃,230℃ and 280℃. Pre-irradiation and quenching have a dramatic effect on the glow curve. It produces a dominant peak at 250℃. A linear relationship between the thermoluminescence intensity of this peak and radiation dose in the range 50~104 roentgens is observed.
摘要:A long detector and two point radiation sources were used to study the character of the calibration curve of radioisotope liquid level gauges.It has been found that, for a specific object to be measured, an approximately linear scale may be obtained by controlling the beam intensity and adjusting the position of the two sources.
摘要:The effect of B4C content in polyethylene-boron carbide on attenuation of neutrons was studied. It has been demonstrated that 10 to 15% of the B4C content in polyethylene-boron carbide could be suitable. The attenuation of neutrons in polyethylene, polyethylene-boron carbide, steel and various combinations of these materials was determined respectively. The data given could be served as references for the design of an effective shield.
摘要:99mTc labelled methylene diphosphonic acid (MDP) , a bone imaging agent, was prepared. After chromatographic examination of purity, it was evaluated on rabbits and subjected to clinical trials on 56 patients of different bone diseases, The localization of MDP in bone was found to be higher than other phosphorous compounds in form of polyphosphate or EHDP. It was also highly concentrated in primary and metastatic bone tumors and was proved to be a satisfactory bone imaging agent.
摘要:Seven tritiated steroids, 1,2-3H-testosterone, 1, 2-3H-cortisol, 6,7-3H-corticosterone, 1,2, 6, 7-3H-progesterone, 6,7-3H-estradioletc,were prepared by the catalytical reduction of dehydrogenated precursor with tritium gas and were purified by thinlayer chromatography and paper chromatography. Products of 25Ci/mM to 85Ci/mM were obtained.t Their radiochemical purity was over 95%.
摘要:This paper describes the distribution and movement of rubidium in cinnamonic soil field of poplar plantation, using 86Rb as a tagging atom.To determine the pattern of distribution and movement in question, a number of monolithic soil samples were taken from the field and analysed, by radioactivity measurement and radioactive autography. The results obtained indicated that the maximum movement of 86Rb in the above-mention soil occured at depths ranging from 6 cm to 15 cm, and that a large amount (83.78~98.73%) of this element was fixed in the upper layer of the soil, to a depth of 3 cm from ground level. Nevertheless, in cinnamonic soil of poplar plantation the movement of 86Rb had nothing to do with irrigation norm.
摘要:Using 14MeV neutron moderated by paraffin, the trace vanadium in oil has been determined by measurement of radioactive intensity of 52V in 51V (n, γ) 52V reactions. The limit of detectability is 1ppm for 5g sample and the standard deviation is less than ±5%. It can also be used to determine the trace vanadium in the natural water combined with the chemical method of drying sample.