反应条件下在线表征装置的研制

武浩; 杨永; 李沛豪; 刘泽邦; 罗阳; 范明慧

doi:10.11889/j.0253-3219.2016.hjs.39.100101

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反应条件下在线表征装置的研制

同步辐射技术及应用 | 更新时间：2021-05-24

- 反应条件下在线表征装置的研制
- A novel apparatus for operando rapid characterization on real reaction: design and application
- 核技术 2016年39卷第10期文章编号：100101
- 作者机构：
  
  1.中国科学院上海高等研究院上海 201210
  2.上海科技大学上海 201210
  3.中国科学院大学北京 100049
- 作者简介：
  
  [ "武浩, 男, 1989年出生, 2011年毕业于中国矿业大学, 现为硕士研究生, 研究领域为催化原位表征", "WU Hao, male, born in 1989, graduated from China University of Mining and Technology in 2011, master student, focusing on operando analysis" ]
  杨永, E-mail:yangyong@shanghaitech.edu.cn YANG Yong, E-mail: yangyong@shanghaitech.edu.cn
- 基金信息：
  
  国家自然科学基金(21573148);上海浦江人才项目(15PJ1405800)
- DOI：10.11889/j.0253-3219.2016.hjs.39.100101
  中图分类号： O652.7
- 收稿日期：2016-07-26，
  
  修回日期：2016-08-29，
  
  纸质出版日期：2016-10
- 稿件说明：
移动端阅览
武浩, 杨永, 李沛豪, 等. 反应条件下在线表征装置的研制[J]. 核技术, 2016,39(10):100101

Hao WU, Yong YANG, Pui Ho Li Jerry, et al. A novel apparatus for operando rapid characterization on real reaction: design and application[J]. Nuclear techniques, 2016, 39(10): 100101
武浩, 杨永, 李沛豪, 等. 反应条件下在线表征装置的研制[J]. 核技术, 2016,39(10):100101 DOI： 10.11889/j.0253-3219.2016.hjs.39.100101.

Hao WU, Yong YANG, Pui Ho Li Jerry, et al. A novel apparatus for operando rapid characterization on real reaction: design and application[J]. Nuclear techniques, 2016, 39(10): 100101 DOI： 10.11889/j.0253-3219.2016.hjs.39.100101.

摘要

多相催化在能源工业中占据重要地位，同时对催化机理的深度认识提出了更高的要求。多数情况下，能够在反应条件下快速得到催化剂的评价和反应动力学相关信息对相关研究是极为理想的。本文介绍了最新研制的一种面向催化剂真实反应条件下具有高度操作灵活性的在线表征微反应装置，能提供液氮温区到500℃的准确控温，实现在真实催化反应条件（常压或高压）质谱在线表征。利用新装置在低温下灵活升温控制的功能，对CO预先还原的Au/TiO

催化剂在-150℃初始条件下完成了程序升温脱附试验。以此为例，新装置在低温区的动态温控功能结合高压条件可以对相关反应提供重要测试表征，是催化常压和高压表征的有力工具。

Abstract

Background:

Heterogeneous catalysis plays an important role in current energy industry

which demands a deep insight of the catalysis mechanism. In most catalyst related studies

online characterization methods that can yield fast evaluation results and kinetics information under industrial reaction conditions are always desired.

Purpose:

A novel apparatus for operando catalytic characterization with high flexibility of controlling reaction conditions is introduced.

Methods:

It performs accurate temperature control from liquid nitrogen region to~500℃ and allows mass spectroscopy (MS) online characterization from atmosphere to high pressure.

Results:

The apparatus is applied for a temperature programmed desorption (TPD) staring from -150℃ on an Au/TiO

catalyst CO pre-adsorbed surface. Results show that the setup performs temperature control with good flexibility at low temperature.

Conclusion:

The apparatus combines features of both wide range temperature controlling and high sensitivity characterization under pressurized conditions

which makes it a powerful tool for understanding catalysis behavior under ambient or high pressure conditions.

关键词

Keywords

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