云母-石墨烯界面纳米尺度受限水层的湿润-去湿润研究

杨硕; 汪颖; 杨海军; 高彦涛; 胡钧; 张金金

doi:10.11889/j.0253-3219.2016.hjs.39.070501

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云母-石墨烯界面纳米尺度受限水层的湿润-去湿润研究

核物理、交叉学科研究 | 更新时间：2021-05-24

- 云母-石墨烯界面纳米尺度受限水层的湿润-去湿润研究
- Studies on wetting-dewetting process of molecularly thin water adlayer confined between graphene and mica interface
- 核技术 2016年39卷第7期文章编号：070501
- 作者机构：
  
  1.中国科学院上海应用物理研究所微观界面物理与探测重点实验室嘉定园区上海 201800;
  2.中国科学院大学北京 100049;
  3.中国科学院上海应用物理研究所堆材料与技术部嘉定园区上海 201800
- 作者简介：
  
  [ "杨硕,男,1992年出生,2013年毕业于重庆大学,现为硕士研究生,研究领域为石墨烯的纳米结构特性", "YANG Shuo, male, born in 1992, graduated from Chongqing University in 2013, master student, focusing on nano-structure of graphene Corresponding author: ZHANG Jinjin, E-mail: zhangjinjin@sinap.ac.cn" ]
  张金金, E-mail:zhangjinjin@sinap.ac.cn ZHANG Jinjin, E-mail:zhangjinjin@sinap.ac.cn
- 基金信息：
  
  国家自然科学基金(No.11405250、No.11375253、No.U1532260、No.11474298);国家重大科学研究计划资助(No.2013CB932801)
- DOI：10.11889/j.0253-3219.2016.hjs.39.070501
  中图分类号： TL99
- 收稿日期：2016-01-25，
  
  修回日期：2016-04-11，
  
  纸质出版日期：2016-07
- 稿件说明：
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杨硕, 汪颖, 杨海军, 等. 云母-石墨烯界面纳米尺度受限水层的湿润-去湿润研究[J]. 核技术, 2016,39(7):070501

Shuo YANG, Ying WANG, Haijun YANG, et al. Studies on wetting-dewetting process of molecularly thin water adlayer confined between graphene and mica interface[J]. Nuclear techniques, 2016, 39(7): 070501
杨硕, 汪颖, 杨海军, 等. 云母-石墨烯界面纳米尺度受限水层的湿润-去湿润研究[J]. 核技术, 2016,39(7):070501 DOI： 10.11889/j.0253-3219.2016.hjs.39.070501.

Shuo YANG, Ying WANG, Haijun YANG, et al. Studies on wetting-dewetting process of molecularly thin water adlayer confined between graphene and mica interface[J]. Nuclear techniques, 2016, 39(7): 070501 DOI： 10.11889/j.0253-3219.2016.hjs.39.070501.

摘要

研究受限于纳米尺度空间的水或者其他分子液体的性质在生物学、材料科学、摩擦学、微流控等领域有重要的意义。但直接通过显微镜观察界面上的纳米尺度液体的润湿动态过程仍然是个挑战。近年来受益于石墨烯等二维晶体材料的发现与发展，由石墨烯作为覆盖材料形成的受限体系为这一问题提供了很好的解决方式。通过原子力显微镜原位成像发现，由石墨烯与云母组成的受限体系中包含水层，一层水层的高度约为0.37 nm，而通过改变周围空气的湿度可以调控受限体系中水层的湿润-去湿润可逆性变化。同时实验中观察到了水层随湿度变化时呈现出的不同的生长方式。平整的石墨烯覆盖层提供了一种新的尺寸可调整的纳米通道，可对纳米尺度的受限水层实现高分辨成像，为纳米流体器件的发展提供了可能性。

Abstract

Background:

The nature of confined water adlayer at nanoscale under ambient is important in biology

material science

and nanofluidics. However

observing wetting and dewetting process of water adlayer on the int

erface directly is still a challenge.

Purpose:

This paper aims to reveal the nature of confined molecularly thin water layer between a graphene layer and a mica substrate.

Methods:

Room temperature

in-situ

Atomic Force Microscope (AFM) observation method was adopted here.

Results:

The results showed that the measured height of the monolayer water film was about 0.37nm

in agreement with the height of a monolayer of ice. The wetting and dewetting process of water adlayers was able to be controlled by changing the ambient humidity. The molecularly thin adlayers can wet the interface through increasing the humidity; otherwise it dewets by reducing the humidity.

Conclusion:

The flat graphene coating offers a novel size-adjustable nano channel

which suggests a new approach for high resolution imaging of confined molecularly thin fluid films. Furthermore

these results can potentially aid in the fabrication of novel nanofluidic devices.

关键词

Keywords

references

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