碳纳米管/聚丙烯酰胺复合水凝胶的制备及性能

叶天南; 刘汉洲; 闫思齐; 畅文娟; 樊文慧; 余枭; 文万信

doi:10.11889/j.0253-3219.2016.hjs.39.020202

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碳纳米管/聚丙烯酰胺复合水凝胶的制备及性能

更新时间：2021-05-24

- 碳纳米管/聚丙烯酰胺复合水凝胶的制备及性能
- Preparation of G-CNTs/PAAm hydrogel and its properties
- 核技术 2016年39卷第2期文章编号：020202
- 作者机构：
  
  苏州大学医学部放射医学与防护学院江苏省放射医学与防护学院重点实验室苏州 215123
  School of Radiation Medicine and Protection, Medical College of Soochow University, Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection, Suzhou 215123, China
- 作者简介：
  
  叶天南,男,1990年出生,2012年毕业于温州医科大学,现为硕士研究生,研究方向为保健物理
  刘汉洲,E-mail:hzhliu@suda.edu.cn
- 基金信息：
- DOI：10.11889/j.0253-3219.2016.hjs.39.020202
  中图分类号： TL75
- 收稿日期：2015-12-08，
  
  录用日期：2016-01-20，
  
  纸质出版日期：2016-01-25
- 稿件说明：
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叶天南, 刘汉洲, 闫思齐, 等. 碳纳米管/聚丙烯酰胺复合水凝胶的制备及性能[J]. 核技术, 2016,39(2):020202

Tiannan YE, Hanzhou LIU, Siqi YAN, et al. Preparation of G-CNTs/PAAm hydrogel and its properties[J]. Nuclear techniques, 2016, 39(2): 020202
叶天南, 刘汉洲, 闫思齐, 等. 碳纳米管/聚丙烯酰胺复合水凝胶的制备及性能[J]. 核技术, 2016,39(2):020202 DOI： 10.11889/j.0253-3219.2016.hjs.39.020202.

Tiannan YE, Hanzhou LIU, Siqi YAN, et al. Preparation of G-CNTs/PAAm hydrogel and its properties[J]. Nuclear techniques, 2016, 39(2): 020202 DOI： 10.11889/j.0253-3219.2016.hjs.39.020202.

摘要

通过活度2.072×10

Bq、剂量率2 kGy·h

-1

的钴-60进行辐照接枝和辐照交联两步法制备了碳纳米管复合水凝胶。使用傅里叶红外光谱(Fourier Transform Infrared spectroscopy

FTIR)、热释重分析(Thermal gravimetricanalysis

TGA)、透射电子显微镜(Transmission electron microscope

TEM)、X射线衍射(X-ray diffraction

XRD)、BET比表面积(Brunauer-Emmett-Teller Specific Surface Area)等方法对样品进行了表征。结果显示

改性后的碳纳米管(Carbon nanotubes

G-CNTs)的管壁出现了明显的链段

其傅里叶红外光谱在1452 cm

-1

和1726 cm

-1

处多了两个吸收峰;碳纳米管复合水凝胶的BET值(30 m

·g

-1

)比聚丙烯酰胺水凝胶的(12 m

·g

-1

)提高了一倍多。实验结果表明丙烯酸被成功接枝到CNTs的管壁上。G-CNTs在凝胶中均匀分散

并提高了复合水凝胶的比表面积和机械强度。

Abstract

Background:

Hydrogel has been widely applied to drug delivery

tissue engineering

water treatment

water retention and separation

etc. Mechanical properties of hydrogel can be improved by combining with other materials without changing its intrinsic properties. Due to the excellent properties of carbon nanotubes (CNTs) such as mechanical strength

hydrogen storage

high specific surface area

they can be applied to selective absorption or separation of hydrogen isotope. CNTs composite hydrogel may combine these excellent properties.

Purpose:

This study aims at a new absorbent material fabricated by irradiation-induced grafting and crosslinking two-steps method.

Methods:

The G-CNTs/PAAm hydrogel with Poly(acrylamide) and CNTs grafted with acrylic acid were fabricated by irradiation-induced grafting and crosslinking two-steps method. Properties of G-CNTs and CNTs were investigated by Fourier transform infrared spectroscopy (FTIR)

thermal gravimetric analysis (TGA)

and transmission electron microscope (TEM). X-ray diffracti

on (XRD) and Brunauer-Emmett-Teller specific surface area (BET) were used to characterize PAAm hydrogel and G-CNTs/PAAm hydrogel. Liquid water and vaporous water absorption ability of G-CNTs/PAAm hydrogel and PAAm hydrogel were tested at room temperature.

Results:

Many objects and pieces appeared on the surface of G-CNTs. There were two new absorption bands at 1 726 cm

-1

and 1 452 cm

-1

in the FTIR spectra of the G-CNTs which indicates that acrylic acid has been successfully introduced onto the surface of CNTs by Co-60 irradiation grafting. According to TGA curves of CNTs and G-CNTs

grafting ratio of G-CNTs (15%) could be calculated. The gel content of G-CNTs/PAAm hydrogel and PAAm hydrogel were 95.6% and 94.7%

respectively. Compared with PAAm hydrogel

two new peaks at 26.5° and 43.2° could be found in the XRD pattern of G-CNTs/PAAm hydrogel associated with CNTs and G-CNTs. The surface area of G-CNTs/PAAm hydrogel with 30 m

·g

-1

was two times larger than that of PAAm hydrogel with 12 m

·g

-1

Conclusion:

Due to the larger surface area of G-CNTs/PAAm hydroge

better vaporous water absorption ability was shown compared with the PAAm hydrogel. Hydrophilic and dispersibility of CNTs in water have been improved and the crystal lattices of CNTs still exist after being grafted. The existence of G-CNTs improves the surface area and stables the structure of G-CNTs/PAAm hydrogel.

关键词

Keywords

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