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中国科学院上海应用物理研究所
纸质出版日期:2009-04-01
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[1]马明旺,陈西良,杨康,杨小敏,刘丹,朱智勇.高能铁离子辐照二氧化硅玻璃产生的缺陷研究[J].核技术,2009,32(04):287-291.
MA Mingwang CHEN Xiliang YANG Kang YANG Xiaomin LIU Dan ZHU Zhiyong. Defects in silica glass irradiated with high energy Fe ions[J]. Nuclear techniques, 2009, 32(4): 287-291.
室温下用紫外-可见吸收光谱、荧光光谱和电子顺磁共振技术测量分析1.157GeV56Fe离子辐照的二氧化硅玻璃
研究了高能重离子辐照产生缺陷的规律。紫外-可见吸收光谱测量结果显示
高能铁离子辐照产生了包括E′心、非桥连氧空穴心(NBOHC)和缺氧心ODC(II)在内的多种缺陷结构。随着离子辐照量的增加
各类缺陷的数量逐渐增大并在高辐照量时趋于饱和。用单离子饱和损伤模型对实验结果进行拟合
获得了各类缺陷的产生截面在90-140nm2。根据缺陷相对数量的变化关系探讨了E′心和NBOHC的产生机制。荧光光谱显示
当以5eV的紫外光激发辐照样品时
观测到三个荧光发射峰
分别位于4.28eV(α带)、3.2eV(β带)和2.67eV(γ带)
α带和γ带的存在证实辐照产生了ODC(II)缺陷。实验发现β带是二氧化硅玻璃中的一种固有缺陷
高能离子辐照可使其部分脱色。电子顺磁共振测量进一步证实了E′心的产生规律。
Silica glass samples were irradiated with 1.157 GeV 56Fe ions to fluence of 0.5×1012
1×1012 and 3.8×1012 ions/cm2.The radiation-induced defects were examined by ultraviolet-visible(UV-Vis)
photoluminescence(PL) spectroscopy and electron paramagnetic resonance(EPR) measurements.Various defects such as E’ centers
non-bridging oxygen hole centers(NBOHC) and oxygen deficient centers
ODC(II)
were induced by the irradiation in production cross-sections of 90-140 nm2.The number densities of the defects increased with the fluence and came to saturation at high fluences.It was found that E’ center and NBOHC were created simultaneously from the scission of strained Si-O-Si band.The PL results showed that the intensity of α and γ band increased with the fluence and tended to saturate at high fluences
while the intensity of β band decreased with increasing fluence.It was concluded that β band belonged to an intrinsic defect in silica glass.EPR measurement confirmed the production of E’ centers with a production cross-section of 138 nm2
which was similar to that found in the UV-Vis measurement.
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