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1. 复旦大学放射医学研究所
2. 中国科学院上海原子核研究所
3. 复旦大学放射医学研究所,上海,200032
4. ,上海,201800
纸质出版日期:2002-07-01
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[1]庞德聆,张晋华,任礼华,钱志林,黄刚.热敏智能径迹膜的研制[J].核技术,2002(07):573-577.
PANG Deling 1 ZHANG Jinhua 2 REN Lihua 1 QIAN Zhilin 1 HUANG Gang 1 1. Preparation of thermosensitive intelligent track membrane[J]. Nuclear techniques, 2002, (7): 573-577.
以N -异丙基丙烯酰胺热敏材料为单体
核径迹微孔膜为基材
用过氧化预辐照接枝技术研制出能控制开关的热敏智能径迹膜。考察了预辐照剂量、接枝温度、单体浓度和反应时间等因素对接枝的影响
以及膜孔开闭动态变化。亚微米级孔径上极薄的热敏接枝层
溶胀与收缩迅速
对温度开关响应更为灵敏
Using N-isopropyl-amide (NIPAAm) thermosensitive function material as monomer and nuclear track microporous membrane (NTMM) as baseline material
a thermosenstitive intelligent track membrane (TsITM) was prepared by the over-oxidization and pre-irradiation grafting techniques. The TsITM can be used to make a micro-switch controlled by temperature. The effects of pre-irradiation dose
grafting temperature
monomer concentration and reaction time on the grafting yield were investigated
and the dynamic range of responsive grafted track pores were observed. To obtain sub-micron responsive grafted track pores only a very thin thermosensitive layer is needed. The TsITM pores are capable of swelling and shrinking rapidly and respond more sensitively to temperature.
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