The SRXRF line scanning analysis technique was used to measure the elements’ content in the Dilingtou Yue procelain sherd of Southern Song Dynasty from glaze to body. It is found that there exists a middle layer between the porcelain glaze and body. And a line scanning analysis comparison was made with the Ru porcelain in Northern Song Dynasty. There are some differences between them and the middle layer of Dilingtou Yue sherd is a little thinner than the Ru sherd’s. And elements’ content distributions in glaze are different from Ru porcelain’s and the changes of contents from the surface to the inner side of glaze are undulatory. The results indicate that the differences may result from the different materials of body and the different kilns.