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1. 昆明理工大学材料科学与工程学院
2. 北京师范大学低能核物理研究所
纸质出版日期:2012-02-01
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[1]冷崇燕,周荣,张旭.Ta离子注入Ti6Al4V合金的抗腐蚀性能[J].核技术,2012,35(02):92-97.
LENG Chongyan1 ZHOU Rong1 ZHANG Xu2 1. Corrosion resistance of Ta~+-implanted Ti6Al4V alloy in Hank’s solution[J]. Nuclear techniques, 2012, 35(2): 92-97.
用注量为1.2×1016、3×1016、1.5×1017、3×1017、4.5×1017/cm2的Ta离子对Ti6Al4V合金进行表面改性
加速电压为146.5 keV。Ta离子注入后
用动电位极化曲线研究其抗Hank’s溶液腐蚀性能
用小角掠射X射线衍射研究其表面物相结构
用X射线光电子能谱分析其腐蚀样品的表面元素化合态。结果表明
Ta离子注入改善了Ti6Al4V合金抗Hank’s溶液腐蚀性能
但试样的腐蚀电流密度并非随Ta离子注量增加而单调减小
试样表面合金层、单质Ta和氧化物
共同形成腐蚀阻挡层
提高其抗腐蚀性能。
Ti6Al4V alloy samples were modified by tantalum ions implantation at the doses of 1.2×1016
3×1016
1.5×1017
3×1017 and 4.5×1017ions/cm2
with an acceleration voltage of 146.5 keV.Potential-dynamic polarization technology was used to investigate corrosion resistance of the Ta+-implanted Ti6Al4V alloy samples in Hank’s solution.Glancing angle X-ray diffraction and X-ray photoelectron spectroscopy were used to characterize of the implanted samples in terms of the phase composition and chemical states of the surface elements
respectively.The Ta ion implantation improves corrosion resistance of Ti6Al4V alloy.However
corrosion current density of the implanted samples was not in a monotonic way of decrease with increasing ion doses.The corrosion resistance improvement of Ta+-implanted Ti6Al4V alloy samples in Hank’s solution is attributed to the corrosion-resistant oxide layer
surface alloy layer produced in the ion implantation
and the Ta in outmost surface of the implanted alloy.
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