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中国科学院上海原子核研究所
收稿日期:1985-09-04,
纸质出版日期:1986-11
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叶良华, 梅周蕾, 叶寅, 等. 辐射制备交联型聚甲基丙烯酸甲酯的研究[J]. 核技术, 1986,09(11):43-45,62.
Lianghua Ye, Zhoulei Mei, Yin Ye, et al. Radiation-induced crosslinking of polymethyl methacrylate[J]. Nuclear techniques, 1986, 09(11): 43-45,62.
有机玻璃,化学名聚甲基丙烯酸甲酯,是一个重要的光学塑料品种。为了使之适应日益发展的现代科学技术的要求,近来各国竞相研究开发新产品,特别期望制备结构交联型的聚甲基丙烯酸甲酯。但目前仅制得轻度交联的或表面浸渍涂层交联的有机玻璃
[1
2]
。
In order to improve the properties of plexi glass and develop new product
the possibility for preparing crosslinking polymethyl methacrylate was tried.
Three methods were carried out:
A. Methyl methacrylate was polymerized in bulk at room temperature.
B. Radiation polymerization of methyl methacrylate in the supercooled liquid phase between the range of -20—-10℃ were observed.
C. Under certain experimental conditions
highly crosslinked polymethyl methaery-late could be formed. Crosslinked polymer of
M
c
=2×10
4
means linear polymer with molecule weight of 2×10
6
which had 100 crosslinking points.
The measurement of
M
c
average molecular weight between crosslinks was established by measuring the swelling capacity of crosslinking polymethyl methacrylate.
姚志亮 , 塑料工业(中国有机玻璃工业联合会成立大会专辑) , 33 ( 1984 )。
朱根元 , 同上 , 42 ( 1984 )。
梅周蕾 等 , 化学世界 , 26 , 12 , 452 ( 1985 )。
E. Cohn-Ginsberg et al . , polymer , 3 , 97 ( 1962 ).
复旦大学化学系高分子教研组 , 高分子实验技术 , 复旦大学出版社 . 1983 年,第 60 - 64 页。
程镕时 等 , 化学学报 , 27 , 3 , 214 ( 1961 )。
叶良华 , 化学世界 , 10 , 317 ( 1980 )
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