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中山大学
收稿日期:1981-07-22,
纸质出版日期:1983-10
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郑裕芳, 余正方, 卢敬业. 复杂穆斯堡尔谱解谱技术[J]. 核技术, 1983,06(5):19-20,26,74,75.
Yufang Zheng, Zhengfang Yu, Jingye Lu. Spectrum stripping techniques in analysis of complex Mössbauer spectra[J]. Nuclear techniques, 1983, 06(5): 19-20,26,74,75.
本文用剥谱方法来解析复杂的穆斯堡尔谱。先从复杂谱中分出一种可能的已知物相物质,若剩余谱仍很复杂,可用相似的方法剥去第二种、第三种物相物质,直到变成较简单的谱,最后采用简单物相谱最小二乘拟合方法来拟合它,求出未知物相谱的特征参数及各物相相对含量。
此方法已用于 "DJS-21"型小容量计算机上。剥谱工作也可在TRS-80或EG3003型微处理机上进行。待分析的复杂谱、剥离的可能的物相谱以及经剥离后剩下的未知物相谱的谱形都可在显示器上清楚地显示出来。
In this paper a method for the analysis of the complex Mössbauer spectra involving computerbased spectrum stripping is described. The reference spectra of various standards are measured and stored in a computer-accessible form. The stripping calculations are performed one by one until the residuals become simple. Then the residual spectra can be analyzed on a least-squares fitting computer program.
This method has already been used on a DJS-21 computer whose capacity is small. Spectrum stripping can also be carried out by a TRS-80 microprocessor.
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