K4[Fe（CN）6]•3H2O在磁场中的穆斯堡尔谱

汪信; 牛均宁; 陈汉文; 忻新泉; 戴安邦; 张毓昌

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K₄[Fe（CN）₆]•3H₂O在磁场中的穆斯堡尔谱

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- K₄[Fe（CN）₆]•3H₂O在磁场中的穆斯堡尔谱
- Mössbauer spectra of K₄[Fe (CN) ₆]•3H₂O in magnetic fields
- 核技术 1984年07卷第4期
- 作者机构：
  
  1.南京大学配位化学研究所
  2.南京大学
- 作者简介：
- 基金信息：
- DOI：
  中图分类号：
- 纸质出版日期：1984-08
- 稿件说明：
移动端阅览
汪信, 牛均宁, 陈汉文, 等. K₄[Fe（CN）₆]•3H₂O在磁场中的穆斯堡尔谱[J]. 核技术, 1984,07(4):44.

Xin Wang, Junning Niu, Hanwen Chen, et al. Mössbauer spectra of K₄[Fe (CN) ₆]•3H₂O in magnetic fields[J]. Nuclear techniques, 1984, 07(4): 44.
汪信, 牛均宁, 陈汉文, 等. K₄[Fe（CN）₆]•3H₂O在磁场中的穆斯堡尔谱[J]. 核技术, 1984,07(4):44. DOI：

Xin Wang, Junning Niu, Hanwen Chen, et al. Mössbauer spectra of K₄[Fe (CN) ₆]•3H₂O in magnetic fields[J]. Nuclear techniques, 1984, 07(4): 44. DOI：

摘要

本文以

Co/Pd为放射源，将K

[Fe（CN）

]•3H

O置于磁场中，磁场方向垂直于

射线方向，得到了不同磁场强度下的穆斯堡尔谱。[Fe（CN）

是典型的抗磁性配离子，Fe

处于

对称性的配位场中，其电子构型为，因而晶体场电场梯度和价电子电场梯度均为零，在无外磁场的情况下，得到单吸收峰的穆斯堡尔谱。当外磁场存在时，由于核Zeeman效应，铁原子核的磁偶极矩与外加磁场发生相互作用，发生了磁分裂现象。根据穆斯堡尔谱实验数据，经理论计算后得到的磁场强度（、8.2、9.6、11.9kGs）与实际施加的外磁场强度（

??x

=0、8.0、10.0、12.0kGs）符合很好。

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