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东北工学院
纸质出版日期:1984-08
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于恩华, 刘月英. 应用穆斯堡尔效应测定Fe-B系及Fe82B13Si5非晶合金的因瓦特性[J]. 核技术, 1984,07(4):25.
Enhua Yu, Yueying Liu. Invar characteristic of Fe-B and Fe82B13Si5 amorphous alloys studied by Mössbauer spectrum analysis[J]. Nuclear techniques, 1984, 07(4): 25.
应用穆斯堡尔效应及正电子湮没技术,对Fe-B(B
15~21
at%)及Fe
82
B
13
Si
5
非晶合金进行了分析,其穆斯堡尔谱呈现参数连续变化的六指峰。经计算机解得的内场分布
P
(
H
i
)表明,
P
(
H
i
)在Fe-B系中与B的含量有关;而
P
(
H
i
)在Fe
82
B
13
Si
5
中则因不同热处理而不同。Fe-B
15
和经过磁场退火的Fe
82
B
13
Si
5
都呈现出高而较窄的
P
(
H
i
)分布,Fe-B
15
系中
P
(
H
i
)的最大内场
H
i
移向低场的一侧。对在Fe
82
B
13
Si
5
中的正电子平均湮没寿命,则经在磁场中热处理后为最大。实验结果表明,Fe-B系的热膨胀系数在B的含量为15%处为极小值;而Fe
L
(低自旋铁百分数)在B含量为15~16%处有极大值。这就指出Fe
8-
B
15
具有大的自发体磁致伸缩
W
s
、极小的热膨胀系数、优异的因瓦特性。我们按马歇尔方程计算其饱和磁矩
M
s
,它比B>15%的Fe-B系要小。从分析可知,因瓦特性好的Fe-B和Fe-B-Si非晶都与高的低自旋Fe百分数、高的
P
(
H
i
)分布有关。
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