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上海化学工业研究院
收稿日期:1981-11-08,
纸质出版日期:1983-02
移动端阅览
王铭钧, 陈永禄. 剂量率和填料量对硅橡胶辐射交联的影响[J]. 核技术, 1983,06(1):17-21,32,75.
Mingjun Wang, Yonglu Chen. The effect of does rate and filler weight on radiation crosslinking of silicone rubber[J]. Nuclear techniques, 1983, 06(1): 17-21,32,75.
本文研究了剂量率及填料量对硅橡胶辐射交联的影响。获得了
G
交
、
G
裂
、
R
g
、
q
0
、
q
0(
s
)
、
q
0(
g
)
、α
0
、
α
0(
s
)
、
α
0(
g
)
、γ、γ
(
s
)
及γ
(
g
)
等交联参数分别与剂量率及填料量成线性关系。
α
0
/
q
0
、
α
0(
s
)
/
q
0(
s
)
及
α
0(
g
)
/
q
0(
g
)
随剂量率及填料量增加而减小。当填料存在时,剂量率对溶胶份数的影响仍符合公式
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http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167325&type=
由于硅橡胶的
q
0
是常数,交联密度(
n
)
-1
与剂量的关系符合方程
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http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167329&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167328&type=
剂量小时剂量率对交联密度的影响很小。
The effect of dose rate and filler weight on radiation crosslinking of silicone rubber (SR)have been investigated in present work.
The values of various crosslinking parameters may be calculated from the equations of crosslinking theory. We found that values are proportional to dose rate and weight of filler. From experimental data it can be seen that:
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http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167335&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167334&type=
values decrease with increase indose rate and filler weight. In the presence of filler
under the condition that total dose remains unchanged the effect of dose rate on sol fraction still follows the equation: logs=logs
o
+B/I
When q
0
is constant
the relation between crosslinking density and dose can be written as
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http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167346&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=34167341&type=
for lower dose the experimental results shows that the equation can be reduced simplified to the well know form
<
n
>
-1
=q
0
R.
The effect of dose rate on crosslinking density is very small at low irradiation dose.
A. Charlesby and S. H. Pinner , Proc. Roy. Soc. , A249 , 367 ( 1959 ).
A. Charlesby , Atomic radiation and polymer , Pergamon Press , 1960 , Chapter 9, 10, 11 and 14 .
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