The positron lifetime has been measured as a function of doped Pb content in(Bi2-xPbx)Ca2.5Nd0.5Cu2O8+y.superconductors.It was found that positron lifetime decreased with the increase of Pb content in 2212 phase.It is believed that Pb substitutes for Bi
which makes some electrons transfer from Cu-O planes or other sites to Bi-O layers
increases the electron density at Bi-O layers and causes Tc to rise.