The ladio-voltaic effect occuring in semiconductor elements was investigated for the tyansfer of radioisotopic decgy energy to electric power.The energy conversion processes were displayed in our experiments. It was shown that the collection ratio is 94% and 72% for the electron-hole pairs ionized by a particles from a 238pu source and by βparticles from a 90Sr source respectively. The energy conversion efficiency was about 16% for a particles and 12.2% for 0 particles.