Simultaneous determination of trace Sm, Eu, Gd and Dy in LiOH by isotope dilution mass spectrometry

Meng Xianhou Bi Songling

您当前的位置：

首页 >

文章列表页 >

Simultaneous determination of trace Sm, Eu, Gd and Dy in LiOH by isotope dilution mass spectrometry

更新时间：2021-04-09

- Simultaneous determination of trace Sm, Eu, Gd and Dy in LiOH by isotope dilution mass spectrometry
- NUCLEAR TECHNIQUES Issue 7, (1993)
- 作者机构：
  
  1. 核工业部北京化工冶金研究院
  2. 核工业部北京化工冶金研究院,北京,101149
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：01 July 1993
- 稿件说明：
移动端阅览
[1]孟宪厚,毕松苓.同位素稀释质谱法测定LiOH中痕量Sm、Eu、Gd和Dy[J].核技术,1993(07):420-426.

Meng Xianhou Bi Songling. Simultaneous determination of trace Sm, Eu, Gd and Dy in LiOH by isotope dilution mass spectrometry[J]. Nuclear techniques, 1993, (7): 420-426.
[1]孟宪厚,毕松苓.同位素稀释质谱法测定LiOH中痕量Sm、Eu、Gd和Dy[J].核技术,1993(07):420-426. DOI：

Meng Xianhou Bi Songling. Simultaneous determination of trace Sm, Eu, Gd and Dy in LiOH by isotope dilution mass spectrometry[J]. Nuclear techniques, 1993, (7): 420-426. DOI：

摘要

建立了LiOH中痕量Sm、Eu、Gd和Dy的同位素稀释质谱法（IDMS）。方法简便

一次涂样可测4个元素。本法测定含Sm、Eu、Gd和Dy分别为0.00820、0.00373、0.00569和0.103μg/g的LiOH试样时的精密度分别为±10％、±5.9％、±9.7％和±5.6％

可以满足核电站用LiOH及LiF的分析需要。

Abstract

A method of determination of trace Sm

Gd and Dy in LiOH and LiF by IDMS is described. Sm

Gd and Dy are separated from other rare earth elements by P507 extractant containing resin. 147Sm

151Eu

160Gd and 160Dy are used as spikes. The ratios of 147Sm/149Sm

151Eu/153Eu

174[GdO]/176[GdO] and 160Dy/162Dy are measured by a mass spectrometer. Precisions of the method for Sm

Gd and Dy are ±10%

± 5.9%

± 9.7% and ±5.6% in samples containing 0.00820 μg/g Sm

0.00373 μg/g Eu

0.00569 μg/g Gd and 0.103 μg/g Dy respectively.A Model ZHT-05A single focusing mass spectrometer is used. Simultaneous determination of the four elements on the same filament is performed. The interoverlaping correlation of 176[GdO]+ with 176[DyO]+ is discussed.

关键词

Keywords

references

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Environmental investigation and suggestion on comprehensive utilization of a copper deposit in Sichuan Province

中子活化分析法测定岩石中的稀土元素l. Na、Sc、Fe和Cr等干扰元素的去除

基性、超基性岩石稀土元素化学前处理中子活化分析

前处理中子活化分析地样中稀土元素的方法

前处理中子活化分析法（PNAA）对广西姑婆山花岗岩体中REE的测定

Related Author

刘磊

Tong Chunhan Liu Lei

冯锡章

汪新福

吴瑜光

孟昭兴

金昱泰

孙兆祥

Related Institution

Institute of Applied Nuclear Techniques, Chengdu College of Geology

北京师范大学

中国科学院高能物理研究所

西南核物理与化学研究所

成都地质学院

AI问答

Address：2019 Jialuo Road, Jiading, Shanghai, China Postal code：201800
Tel：021-39194977 Email：LHB@sinap.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 沪ICP备05005479号-1 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
Total Visits：880771 Visits Today：298

⁰