Synergistic extraction of U(VI) and separation of U(VI) and Th(IV) from nitric acid with HBMPPT and DOSO in toluene

您当前的位置：

首页 >

文章列表页 >

Synergistic extraction of U(VI) and separation of U(VI) and Th(IV) from nitric acid with HBMPPT and DOSO in toluene

更新时间：2021-03-12

- Synergistic extraction of U(VI) and separation of U(VI) and Th(IV) from nitric acid with HBMPPT and DOSO in toluene
- NUCLEAR TECHNIQUES Issue 1, (2000)
- 作者机构：
  
  1. 海军医学研究所!上海　２００４３３
  2. 中国科学院上海原子核研究所!上海　２０１８００
  3. 海军医学研究所!上海　２００４３３中国科学院上海原子核研究所!上海　２０１８００
- 作者简介：
- 基金信息：
- DOI：
  CLC： TL27
- Published：01 January 2000
- 稿件说明：
移动端阅览
[1]余绍宁,赵山银,包伯荣.HBMPPT-DOSO-甲苯体系对铀(Ⅵ)的萃取及铀(Ⅵ)、钍(Ⅳ)之间的分离[J].核技术,2000(01):48-51.

Synergistic extraction of U(VI) and separation of U(VI) and Th(IV) from nitric acid with HBMPPT and DOSO in toluene[J]. Nuclear techniques, 2000, (1).
[1]余绍宁,赵山银,包伯荣.HBMPPT-DOSO-甲苯体系对铀(Ⅵ)的萃取及铀(Ⅵ)、钍(Ⅳ)之间的分离[J].核技术,2000(01):48-51. DOI：

Synergistic extraction of U(VI) and separation of U(VI) and Th(IV) from nitric acid with HBMPPT and DOSO in toluene[J]. Nuclear techniques, 2000, (1). DOI：

摘要

以个苯甲酰基－２，４二氢－５－甲基－２－苯基－３Ｈ－吡唑硫酮－３（ＨＢＭＰＰＴ）为萃取剂、二正辛基亚砜（ＤＯＳＯ）为协萃剂，研究其在硝酸介质中对铀（Ⅵ）的萃取行为，以及萃取剂浓度、酸度等各种因素对萃取分配比的影响，以确定两种萃取剂的协同萃取及分离效果。结果表明，ＨＢＭＰＰＴ和ＤＯＳＯ有较好的协同萃取效果，一定条件下，铀（Ⅵ）、钍（Ⅳ）的分离系数可达５２３。

Abstract

(Shanghai institute of Nuclear Research

the Chinese Academy of Sciences

Shanghai 201800)The synergistic extraction of U（VI） and separation of U（VI） and TI（IV） from nitricacid solution by HBMPPT （4-benzoyl-2

4-dihydro-5-mepgrazol-3-thione） and DOSO （di-n-octyl sulfoxide） in toluene was studied. Theextraction ability of HBMPPT was not so high as that of its parent （HBMPP）

butwhen a little DOSO was added in

the ability to extract U（VI） was improved rapidly.The syndrgistic extracted complexes may be presented as a mixture of UO

BMPPT

BMPPT. DOSO

（BMPPT）

and UO

（BMPPT）

. DOSO forU（VI）. When HBMPPT-DOSO was used to separate U（VI） from TI（W）

the separationcoefficient reached 523 under certain condition.

关键词

Keywords

references

Views

110

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study on new extractants for actinides and lanthanides separation (III) ——studies on the synthesis of a new extractant HMBMPPT and its extraction for U(VI)

N-Decanoylmorpholine as novel extractant for HNO₃ and U（Ⅵ）

Studies on extraction separation of Am(Ⅲ) and Ln(Ⅲ) from nitric acid media with HBMPPT and TOPO in toluene

Effect of TBP on extraction of uranium(VI) with N,N-dibutyloctylaminde

Preparation of pure ²²³U from aged МnO₂ precipitate containing ²³³Pa and irradiated ThO2

Related Author

2 HANG Jianzhong2 BAO Borong1

2 HUANG Wei2 CHEN Jie2 1

黄炜

陈杰

CAO Weiguo1

曹卫国

包伯荣

YANG Xingcun 1 BAO Borong 2 CAO Weiguo 2 1

Related Institution

Shanghai Institute of Nuclear Research, the Chinese Academy of Sciences, Shanghai 201800) 2

上海大学

上海大学上海

上海大学理学院

AI问答

Address：2019 Jialuo Road, Jiading, Shanghai, China Postal code：201800
Tel：021-39194977 Email：LHB@sinap.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 沪ICP备05005479号-1 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
Total Visits：880886 Visits Today：413

⁰