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1. 上海大学射线应用研究所
2. 中国原子能科学研究院放射化学研究所
4. ,北京,102413
Published:01 April 2004
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[1]王锦花,包伯荣,吴明红,孙喜莲,张先业,胡景炘,叶国安.N,N-二甲基羟胺辐解产生的气态烃类的定性和定量分析[J].核技术,2004(04):301-304.
WANG Jinhua1 BAO Borong1 WU Minghong1 SUN Xilian1 ZHANG Xianye2 HU Jingxin2 YE Guoan2 1. Qualitative and quantitative analysis of light hydrocarbons produced by radiation degradation of N, N-dimethyl hydroxylamine[J]. Nuclear techniques, 2004, (4): 301-304.
[1]王锦花,包伯荣,吴明红,孙喜莲,张先业,胡景炘,叶国安.N,N-二甲基羟胺辐解产生的气态烃类的定性和定量分析[J].核技术,2004(04):301-304. DOI:
WANG Jinhua1 BAO Borong1 WU Minghong1 SUN Xilian1 ZHANG Xianye2 HU Jingxin2 YE Guoan2 1. Qualitative and quantitative analysis of light hydrocarbons produced by radiation degradation of N, N-dimethyl hydroxylamine[J]. Nuclear techniques, 2004, (4): 301-304. DOI:
报道了用三氧化二铝毛细柱与氢火焰离子化检测器联用的气相色谱法
定性定量分析了N
N-二甲基羟胺水溶液辐解产生的气态烃类。结果表明
辐照剂量为10—1000kGy时
N
N-二甲基羟胺水溶液辐解产生的气态烃类有甲烷、乙烷、乙烯、丙烷、丙烯和正丁烷
当N
N-二甲基羟胺浓度为0.2mol/L时
甲烷的体积分数为9.996×10-6—247.5×10-6
乙烷、丙烷和正丁烷的体积分数较低
而乙烯和丙烯的体积分数则更低。甲烷的体积分数随剂量的增加而增加
而乙烷、乙烯、丙烷、丙烯和正丁烷的体积分数随剂量变化不明显。
This paper reports the qualitative and quantitative analysis of light hydrocarbons produced by radiation degradation of N
N-dimethyl hydroxylamine. These analyses were performed on the gas chromatograph
in which porous layer open tubular column coated with aluminum oxide and flame-ionization detector are used. For the doses between 10 and 1000kGy
the light hydrocarbons produced by radiation degradation of N
N-dimethyl hydroxylamine are methane
ethane
ethene
propane
propene and n-butane. When the concentration of N
N-dimethyl hydroxylamine is 0.2mol/L
the volume fraction of methane is (9.996— 247.5)×10-6
the volume fraction of ethane
propane and n-butane is lower and that of ethene and propene is much lower. With the increase of dose the volume fraction of methane is increased but the volume fraction of ethane
ethene
propane
propene and n-butane is not obviously changed.
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