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1. 中国科学技术大学地球和空间科学系,中国科学技术大学地球和空间科学系,中国科学技术大学地球和空间科学系,中国科学技术大学地球和空间科学系,中国科学技术大学地球和空间科学系,合肥,230026
2. 中国科学院地球环境研究所黄土与第四纪国家重点实验室,西安710054,合肥,230026
3. 中国科学院地球环境研究所黄土与第四纪国家重点实验室,西安710054,合肥230026,合肥230026,合肥,230026
Published:01 March 2003
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[1]王俊新,彭子成,刘桂建,房明惠,桂和荣.~(40)K-~(40)Ca法的初步研究[J].核技术,2003(03):197-201.
WANG Junxin1, 2 PENG Zicheng1, 2 LIU Guijian1 Fang Minghui 1 Gui Herong1 1. A preliminary study on dating and tracing of the 40K-40Ca system[J]. Nuclear techniques, 2003, (3): 197-201.
报道了样品中钾、钙化学分离和纯化
以及质谱测定流程的建立。测试了国家球团矿标样W7220和W7107、国家40K-40Ar法标准矿物黑云母(ZBH-25)和角闪石(ZBJ)的钾钙含量
以及国际二级钙标样Tachiti和国家钾含量标样的钙和钾同位素比值。实测结果与相应的标称值在误差范围内一致。在此基础上
用实验所得的两组黑云母和角闪石的(40Ca/42Ca) 和 (40K/42Ca)数据
构筑了40K-40Ca法等时线年龄为(133.532.1)Ma
此与标称值年龄132.7Ma在误差范围内一致。而所得的初始值(40Ca/42Ca)i为151.4160.003
相应的xCa 值为+26.5
示踪了该矿物组合的原岩具有陆源性质
为固体地球化学的研究提出了新的判据。
The K and Ca contents in the national standards of pellets (W7220
W7107)
biotite (ZBH-25) and hornblende (ZBJ)
as well as
the K and Ca isotopic ratios of the national K standard and an international standard (Tachiti) have been determined by using mass spectrometry and atomic absorption spectrometry . The measured results are in agreement with the standard values within a reasonable error range. On the basis of the standard measurement
the slope of the regressive line between (40K/42Ca) and (40Ca/42Ca) data is equal to 0.068730.01732
corresponding to the age of (133.532.1)Ma
which is consistent with the 132.7Ma in the error range reported by using the 40K-40Ar method. The primitive ratio (40Ca/42Ca)i deduced from the isochrone is 151.4160.003
corresponding to +26.5 of the xCa value. It means that the original rock of the biotite and hornblende minerals appears in the terrestrial behavior.
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