Radiation stability of extractants containing phosphrus used in nuclear recycling

ZHANG Ping LIANG Junfu XIN Renxuan SONG Chongli

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Radiation stability of extractants containing phosphrus used in nuclear recycling

更新时间：2021-03-12

- Radiation stability of extractants containing phosphrus used in nuclear recycling
- NUCLEAR TECHNIQUES Issue 12, (2003)
- 作者机构：
  
  1. 清华大学核能技术设计研究院
  2. 清华大学核能技术设计研究院,北京,100084
- 作者简介：
- 基金信息：
  
  国家“九五”攻关项目(96—A18—02)资助
- DOI：
  CLC： TL249
- Published：01 December 2003
- 稿件说明：
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[1]张平,梁俊福,辛仁轩,宋崇立.核燃料循环中所用含磷萃取剂的辐照稳定性研究[J].核技术,2003(12):940-945.

ZHANG Ping LIANG Junfu XIN Renxuan SONG Chongli. Radiation stability of extractants containing phosphrus used in nuclear recycling[J]. Nuclear techniques, 2003, (12): 940-945.
[1]张平,梁俊福,辛仁轩,宋崇立.核燃料循环中所用含磷萃取剂的辐照稳定性研究[J].核技术,2003(12):940-945. DOI：

ZHANG Ping LIANG Junfu XIN Renxuan SONG Chongli. Radiation stability of extractants containing phosphrus used in nuclear recycling[J]. Nuclear techniques, 2003, (12): 940-945. DOI：

摘要

对核燃料后处理以及高放废液处理中所用的含磷萃取剂的辐照稳定性已经进行了广泛的研究。对正辛基苯基-N

N’-二异丁基胺甲酰甲基氧化膦（CMPO）、二（2-乙基己基）磷酸（DEHPA）以及混合三烷基氧化膦（TRPO）等的辐照稳定性的研究进行了综述。主要介绍了CMPO、DEHPA和TRPO的辐解产物;辐照对萃取和保留的影响以及辐照后溶剂的净化方法。

Abstract

Radiation stability of extractants containing phosphorus used in nuclear reprocessing has been widely investigated. Studies on the radiation stability of tributyl phosphate （TBP）

octyl-phenyl-N

N’-diisobutylcalbamoy-Imethylphosphine oxide （CMPO）

di（2-ethylhexyl） phosphorous acid（DEHPA）

and trialkylphosphine oxide（TRPO）

were reviewed. The radiolytic products of CMPO

DEHPA and TRPO

the effects of radiation on extraction and retention

and cleaning methods of irradiated solvents were introduced.

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