Mössbauer studies on F-series nitrogen fixation model compounds

Youtong Wang

您当前的位置：

首页 >

文章列表页 >

Mössbauer studies on F-series nitrogen fixation model compounds

更新时间：2022-09-13

- Mössbauer studies on F-series nitrogen fixation model compounds
- Nuclear Techniques Vol. 07, Issue 5, (1984)
- 作者机构：
  
  中国科学院福建物质结构研究所
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Received：06 September 1983，
  
  Published：1984-10
- 稿件说明：
移动端阅览
Youtong Wang. Mössbauer studies on F-series nitrogen fixation model compounds[J]. Nuclear techniques, 1984, 07(5): 37-38,73,74.
DOI：

Youtong Wang. Mössbauer studies on F-series nitrogen fixation model compounds[J]. Nuclear techniques, 1984, 07(5): 37-38,73,74. DOI：

摘要

实验测定F-系固氮模拟物的穆斯堡尔参数，总误差小于±1%。确定了该化合物的分子式是（Et

N）

[Mo

（SR）

]。从穆斯堡尔谱可以看出化学位移和四极裂距是

的线性函数，阐明Mo与Fe类质同象替代。从我们的实验结果推论合成的F-系固氮模拟物是单类立方烷构型。

Abstract

An experimental determination of Mössbauer parameters of F-series nitrogen fixation model compounds has been carried out with total errors less than±1%. It has been found that the molecualr formula of this compound is (Et

[Mo

4-x

(SR)

]. From the Mössbauer spectrum it can be seen that the isomer shift and quadrupolar splitting values are linear functions of X

which indicates the isomorphous substitution of Mo and Fe. It is deduced from our experimental results that the F-series nitrogenn fixation model compounds synthesized is a mono cubane-like configuration.

关键词

Keywords

references

中国科学院物质结构研究所固氮小组，科学通报， 20 ， 12 ， 540 （ 1975 ）。

卢嘉锡，物质结构研究所通讯， 1 ， 1 （ 1979 ）。

同上， 1 ， 41 （ 1979 ）。

Sei Otsuka and Masato Kamata , International symposium molybdenum chemistry of biological significance ( Japan ), 1979 .

R. B. Frankal et al ., J. Phys. , 35 , C6 , 107 ( 1974 ).

E. J. Laskouski et al ., J. Amer. Chem. Soc ., 100 , 5322 ( 1978 ).

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

No data

Related Author

No data

Related Institution

No data

AI问答

Address：2019 Jialuo Road, Jiading, Shanghai, China Postal code：201800
Tel：021-39194977 Email：LHB@sinap.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 沪ICP备05005479号-1 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
Total Visits：880007 Visits Today：529

⁰