Inves tigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis

Zuguo Ding; Zhifang Chai; Jiamo Fu; Guoying Sheng; Qing Lin; Di Wu

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Inves tigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis

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- Inves tigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis
- Nuclear Techniques Vol. 13, Issue 4, (1990)
- 作者机构：
  
  1.中国科学院高能物理研究所
  2.中国科学院贵阳地球化学研究所
  3.地质矿产部石油地质中心实验室
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Received：12 July 1988，
  
  Published：1990-04
- 稿件说明：
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Zuguo Ding, Zhifang Chai, Jiamo Fu, et al. Inves tigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis[J]. Nuclear techniques, 1990, 13(4): 203-209.
DOI：

Zuguo Ding, Zhifang Chai, Jiamo Fu, et al. Inves tigation on trace elements in crude oil and organic matter extracted from rocks with instrumental neutron activation analysis[J]. Nuclear techniques, 1990, 13(4): 203-209. DOI：

摘要

本工作利用仪器中子活化分析方法，对我国八大油田及华南上扬子地区下古生界生油、储油岩系的有机分离沥青质的近七十个样品进行了研究，得到了Al、As、Au、Ba、Br、Cl、Co、Cr、Cs、Cu、Fe、Hf、I、Ir、Mg、Mn、Mo Na、Ni、Rb、S、Sb、Sc、Se、Sr、Th、Zn、V和部分REE近四十个元素的丰度值。这方法可以排除因灰化而导致的As、Cl、S、Se和Sb等元素的丢失；色谱分离使研究各有机组分中微量元素的分布成为可能。同时初步讨论了我国原油中微量元素的基本规律。

Abstract

Solvent extraction

column chromatography and instrumental neutron activation analysis (INAA) have been used to investigate the trace elements in crude oil

organic matter extracted from rocks and their related fractions. With these methods

about 70 crude oil samples from eight different oil fields in China and 6 extracted asphaltene samples of the lower paleozoic from the upper Yangtze region have been analyzed

and about 40 elements of interest have been determined. Those elements include Al

V and parts of REE. The experimental results show that the method possesses several advantages

i.e.non-destructive

multi-elements

sensitive

precise and accurate. Without ashing samples

the loss of volatile elements such as Cl

Se and Sb are avoided. The column chromatography makes it possible to study the distributions of trace elements in different fractions of crude oil and organic matter extracted. Meanwhile

the characters of trace elements in them have also been discussed in this paper.

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references

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