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浙江农业大学原子核农学研究所
Received:15 December 1988,
Published:1989-07
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Jinhe Sun, Jianying Gan, Xingming Li, et al. RESEARCH ON BOUND RESIDUES OF CARBOFURAN IN PADDY RICE/FISH ECOSYSTEM UTILIZING NUCLEAR TECHNIQUES[J]. 核技术, 1989, 12(7): 419-426.
14
C-呋喃丹在水中的残留量很低. 在土壤、鱼和植株各部位的
14
C-残留物绝大部分呈结合态. 收获时
在上述各部位中
结合残留分别占86.55%
77.91%和70.45%. 这些结合残留物在酸解时会释出显著量的
14
C
其中仅小部分为有机溶性. 就土壤言
母体又是主要的
其次是3-0-呋喃丹酚
3-O-呋喃丹和3-OH-呋喃丹等. 在高温时
残留在土壤中的
14
C又会进一步释放出来. 在330℃时释出的
14
C远低于750℃
且主要是有机溶性的
在750℃释出的主要是
14
CO
2
.
The residue of
14
C-carbofuran in water was very low though the application rate was five times of that in the common case.Only a small part of the
14
C-residues in water were organic soluble products
in which most of them were carbofuran. The majority of
14
C-residues recovered in soil
fish and plant (cargo rice
husk
straw and roots) were unextractable (bound) and the percentages of bound residues were 86.55%
79.91% and 70.45%(73.26%
67.90%
64.22% and 76.41%)at harvest respectively The bound residues could be hydrolysed with HC1
and released significant amounts of the bound
14
C. The percentages of
14
C released from fish cargo rice
straw
roots
husk and soil at harvest were 91.60%
82.13%
30.47%
24.69%
18.67% and 17.30% respectively. Tne organic soluble portion of the
14
C released in all items analysed were small
and in which
the parent compound carbofuran was found as the greatest in quantity and decreased with time
next came to 3-hydroxy-carbofuran
3-keto-carbofuran and others (unknown) for soil.
14
C in hydrolysed soil could be further released under high temperature distillation (330℃
500℃ and 750℃). Percentages of
14
C released were 21.44% to 28.49%30 to 76 days after the treatment
among which
the majority was organic soluble
14
C at 330℃
while
14
CO
2
was predominant at 500℃ and 750℃.
A. Hussain , et al . , Quantification, Nature and bioavailability of bound 14 C-pesticide residues in soil, plants and food , ( Proc. Panel Gainesville, 1985 ), IAEA , Vienna , 1986 , p. 23 .
S.U. Kuan , J . Agrie. Food Chem. , 30 ( 1982 ), 175 .
E.L. Zorgani et al . , Quantification, Nature and bioavailability of bound 14 C-pesticide residues in soil, plants and food , ( Proc. Panel Gainesville, 1985 ), IAEA , Vienna , 1986 , p. 51 .
J. DEC , et al . , ibid , p. 93 .
J.H. Caro et al . , J. Agric. Food Chem. , 21 ( 1973 ), 1010 .
G. D. Stration et al . , Quantification, Nature and bioavailability of bound 14 C-Pesticide residues in Soil, plants and food , ( Proc. Panel Gainesville, 1985 ), IAEA , Vienna , 1986 , p. 71 .
S.U. Khan , J . Agric. Food Chem. , 31 ( 1984 ) 1189 .
S. Hiromi et al . , J . Agric. Food Chem. , 31 ( 1983 ), 96 .
T.R. Nelson , J. Agric. Food Chem. , 28 ( 1980 ), 98 .
S.S. Gill , Bull. Envion. Toxicol. , 25 ( 1980 ), 697 .
R.L. Metcalf et al . , J . Agric. Food Chem. , 16 ( 1968 ). 301 .
H.W. Dorough , J . Agric. Food Chem. , 16 ( 1968 ), 319 .
J.H. Sun et al . , Pesticides: Food and environmental implications , IAEA , Vienna , 1988 , p. 235 .
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