Mössbauer study of Chinese ancient bronze mirrors

Peiqun Zhang; Guiquan Ji; Huhou Li

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Mössbauer study of Chinese ancient bronze mirrors

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- Mössbauer study of Chinese ancient bronze mirrors
- Nuclear Techniques Vol. 09, Issue 2, (1986)
- 作者机构：
  
  1.中国科学院高能物理研究所
  2.中国社会科学院考古研究所
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Received：12 June 1984，
  
  Published：1986-02
- 稿件说明：
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Peiqun Zhang, Guiquan Ji, Huhou Li. Mössbauer study of Chinese ancient bronze mirrors[J]. Nuclear techniques, 1986, 09(2): 7-10,58.
DOI：

Peiqun Zhang, Guiquan Ji, Huhou Li. Mössbauer study of Chinese ancient bronze mirrors[J]. Nuclear techniques, 1986, 09(2): 7-10,58. DOI：

摘要

本文用

119

Sn穆斯堡尔谱学对中国古代青铜镜进行了研究。发现在铜镜表面锡以Sn

4＋

氧化物状态存在，而在铜镜内部则以Cu-Sn-Pb合金状态存在。铜镜表面是否具有“黑漆古”似与表面层中锡的存在状态无必然联系。由铜镜表面区分层的

119

Sn内转换电子穆斯堡尔谱的分析可知，锡的存在状态由表面的Sn

4＋

氧化物逐渐过渡到内部的Cu-Sn-Pb合金，但在距离表面的不同深度区域，这两种物相相对含量比的变化速度并不完全相同。

Abstract

The Chinese ancient bronze mirrors have been studied using

119

Sn Mössbauer spectroscopy. It is found that tin is in the state of Sn

oxide in the surface of bronze mirror and Cu-Sn-Pb alloy state in the interior body. It is unlikely that the form of tin existing in the surface of bronze mirror has certain relations with the existance of the shiny black surface.

119

Sn conversion electron Mössbauer measurements are also used to investigate the variation of relative amounts between the two tin-containing components with the depth from the surface. It is gradually changed from Sn

oxide in the surface to Cu-Sn-Pb alloy in the interior. But the variation rate of the ratio between the relative amounts of the two components is not constant.

关键词

Keywords

references

W. T. Chase and U. M. Franklin , Art Orientalis , 6 , 215 ( 1979 ).

M. Takeda et al . , Radiochem. Radioanal. Letters , 29 , 4 , 191 ( 1977 ).

C. M. Yagnik et al . , Nucl. Instr. Meth. , 114 , 1 ( 1974 ).

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