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脒基硫脲是一种氮肥增效剂。它是白色针状结晶,熔点170℃,其分子量为ll8,分子式为C
2
H
6
N
4
S,结构式为
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。它具有较好的抑制硝化细菌的效能。我所和江西省轻化工业科学研究所协作试制了
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C-脒基硫脲,为同位素示踪残留试验提供了产品。
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C-dicyanodiamide was prepared by the reaction of hydrogen sulfide using isoprepanol as solvent and p-quinone dioxime as catalyst in antoclave on a water-bath at 95
℃
. The product had a yield of 60% with chemical purity of 85%
and radiochemical purity of 92.5%.
江西轻化工业研究所 , 脒基硫脲合成试验报告,内部资料 ( 1975 ).
特许公报 , 1939,1971 .
A. Murray and D. L. Williams , Organic Syntheses with isotopes (1) , N. Y., Interscience , 1958 , P 592 .
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