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本文介绍用化学合成法制得D-葡萄糖-6-
14
C。产率按碳酸钡-
14
C计算为18.3%,比度为4.6mCi/m
M
。产品经鉴定为化学纯与放化纯,
14
C标记在第6位碳原子上。D-萄葡糖-6-C
14
在贮存中的稳定性也进行了研究。
D-glucose-6-
14
C was prepared by chemical synthesis from
14
C-barium carbonate. The yield was 18.3%
with specific activity of 4.6mCi/m
M
. The product was of high purity. The labeled position of
l4
C atom was proved by the degradation method. The stability of product in storing was also studied.
R. Schaffer and H. S. Isbell , J. Research of The National Bureau of Standards , 56 , 191 ( 1956 ).
D. D. Van Slyke , Anal. Chem. , 26 , 1706 ( 1954 ).
E. J. Bourne , J. Chem. Soc. , 5153 ( 1960 ).
G. O. Phillips and K. W. Davics , J . Chem. Soc. , 2654 ( 1965 ).
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